I had the same issue with python 2.7 and opencv 2.4.10. I copied the opencv_ffmpeg2410_64.dll file from C:\Applications\opencv\build\x64\vc10\bin into the python path (mine is at C:\Users\mohammad\Anaconda) and it was solved!
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I had the same issue with python 2.7 and opencv 2.4.10. I copied the opencv_ffmpeg2410_64.dll file from C:\Applications\opencv\build\x64\vc10\bin into the python path (mine is at C:\Users\mohammad\Anaconda) and it was solved!